In mathematics and physics, the Kramers-Kronig relations describe the relation between the real and imaginary part of a certain class of complex-valued functions. The requirements for a function f(ω) to which they apply can be interpreted as that the function must represent the Fourier transform of a linear and causal physical process. If we write
- f(ω) = f1(ω) + if2(ω),
where f1 and f2 are real-valued "well-behaving" functions, then the Kramers-Kronig relations are
.
The Kramers-Kronig relations are related to the Hilbert transform, and are most often applied on the permittivity ε(ω) of materials. However, it must be noticed that in this case,
- f(ω) = χ(ω) = ε(ω) / ε0 - 1,
where χ(ω) is the electric susceptibility of the material. The susceptibility can be interpreted as the Fourier transform of the time-dependent polarization in the material after an infinitely short pulsed electric field, in other words the impulse response of the polarization.